March 18, 2014
Chicken fat, pork fat or beef fat –– none is the
cornerstone of a healthful diet –– but animal fats, including those from alligators,
could give an economical, ecofriendly boost to the biofuel
industry, according to researchers who reported a new method for biofuel
production here today. The report, following up on their earlier study on the
potential use of gator fat as a source of biodiesel fuel, was part of the 247th
National Meeting of the American Chemical Society, the world’s largest
scientific society.
The meeting, attended by thousands of scientists,
features more than 10,000 reports on new advances in science and other topics.
It is being held at the Dallas
Convention Center and
area hotels through Thursday.
“Conversion of animal fat to biodiesel has been around
for some time, but the traditional biodiesel process generates significant
quantities of solid waste,” said Thomas Junk, Ph.D. “Our new method creates
hardly any such residues.” He also said that the new study concluded that using
fat from such common sources as chicken, pork and beef could be much more
practical for commercial implementation than from the limited amount available
from alligators and could be just as effectively turned into biodiesel.
Junk, who is with the University
of Louisiana at Lafayette , explained that in the earlier
alligator fat study, they used a batch reactor, but switched to a flow reactor
to process the fat in the new work. “We set up a flow reactor, and the reaction
converting alligator fat to biodiesel happened within a few minutes,” said
Junk. “That’s important for commercial manufacturing, where you want to produce
as much fuel as quickly as possible.” With batch reactors, reactions occur
one-at-a-time in discrete batches. But in a flow reactor, the reactions run in
a continuous stream.
He said that fuel produced from various animal fats is
very similar to biodiesel manufactured by traditional, well-established methods,
such as producing ethanol from corn. “So this approach is not really about a
brand-new fuel, but the manufacture of a known type of fuel (biodiesel) using a
more efficient, less wasteful process that largely eliminates solid-waste
byproducts,” he explained. This method does not require a catalyst, which
creates a residue, he explained. Instead, they use “supercritical methanol,”
which is heated to pressures and temperatures high enough to take on properties
in between those of a liquid and a gas.
Another advantage of the supercritical method is that
the fat doesn’t have to be extracted for the process to work, Junk said. It can
be used in its raw form. Crude fat and methanol would be homogenized into a
slurry (semiliquid mixture) and pumped into the system. This should be a
straight-forward, simple process for a manufacturer, he added.
In the earlier study, Junk and the team noted that
most of the 700 million gallons of biodiesel produced in the United States
(2008 data) came from soybean oil. But there has been growing
concern that using soybeans and other food crops for this purpose could raise
food prices.
In searching for alternative biodiesel
materials, they discovered that waste alligator fat, millions of pounds of
which are thrown out every year, could also work. Their experiments showed that
oil extracted from alligator fat can easily be converted into biodiesel. And
now they plan to test other waste animal fats, such as those from chickens and
cows. They predict that these fats also can be easily converted to biodiesel
with the flow reactor system.
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